Tephra is defined as the gravel and
mineral particles which are erupted from a volcano and the granule less than 2
mm in diameter. At the explosive of the volcanic activity, the solid rocks and
lava are broken down into the fine particles and formed to volcanic ash. In the
mix materials of some pozzolana, there are active ingredients, such as a
certain number of active silica, activated titanium oxide.
The coal takes the domination of China's
energy structure, and one of the main sources of air pollution is the nitrogen
oxide which is produced by the consumption of coal; the nitrogen oxide will not
only cause acid rain, photochemical smog and other issues which damages to the
global environment, but also seriously endanger human health. Conventional manufacturing
of honeycomb catalyst is taking tungsten trioxide and nanoscale titanium
dioxide as the main raw material, and mixing with water, binders, extrusion
aid, reaming, lubricants, glass fibers and so on to fully kneaded to obtain a
plastic pug, then extruded to wet honeycomb catalyst, finally get the molded
catalyst after drying and calcining.
tephra and denitration catalyst
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Study has found that the tungsten trioxide
denitration catalyst containing tephra which the components include: nano
titanium dioxide powder 72~81, volcanic tephra 5~15, ammonium metatungstate 0.9~3,
ammonium metavanadate 0.7~2, monoethanolamine 2~6, carboxymethyl cellulose 2,
Polyoxyethylene of 2, 1~3 lanthanum nitrate (Remarks: the unit is part). The
preparation method is as follows:
1. Mix the monoethanolamine, deionized
water and ammonium metavanadate together, and fully dissolved by heating and
stirring to prepare a solution of ammonium metavanadate;
2. Respectively dissolve lanthanum nitrate
and ammonium metatungstate in water at room temperature, continually stirring
for 1 hour to obtain the solution of ammonium metatungstate and lanthanum
nitrate;
3. Mix the tephra, nano titanium dioxide
with deionized water, ammonium metavanadate and ammonium metatungstate
solution, polyethylene oxide, lanthanum nitrate solution for high-speed mixing
evenly, then standing for 1-12 hours to obtain pug;
4. Warmed and dried the pug;
5. Calcine the dried pug, which is obtain
the tungsten trioxide denitration catalyst products containing tephra after
calcined at a maximum temperature of 600°C for 30 hours.
Studies have shown that it can reduce the
high amount of conventional titanium dioxide by adding volcanic tephra, thereby
reducing costs; tungsten trioxide decomposed from the calcination of ammoniummetatungstate in the production process; the cost will be reduced, compared
with directly using nanoscale titanium dioxide which containing tungsten
trioxide as a raw material; the added polyethylene oxide in calcined product
improving pore volume and distribution of the products, increasing the specific
surface area, thus to effectively improve the denitration performance;
therefore, we will know this kind of tungsten trioxide denitration catalyst
containing tephra has a low manufacturing cost, high specific surface area of
catalyst products, wide operating temperature, and has the advantage of good
catalytic denitration performance at the same time.
Chinatugnten Online Tel:86-592-512-9696 Fax:86-592-512-9797 Email:sales@chinatungsten.com
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